Methodecalvulsdefinitive.pdf


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´
Hele

Heff

Heff =

n
X

(hµ + Veff (µ))

µ

Veff µ

µ

Heff Ψ = EΨ

Ψ

Φi

| Ψ(1, 2, ......, n) >=| Φ1 Φ2 ...Φi ......Φn >

H(1)Φi (1) = εi Φi (1)

H(1) = h(1) +

m
X

Ji (1)

i

εi

Φi

χp

| Φi >=

m
X

Cin | χn >

n=1

h

N

h(1) =

−4µ X ZI

2
rµI
I=1

Ji (1)

Ji (1) =

Z

Φ∗i (2)

1
Φi (2)dτ
r12

HSCF Φi (1) = εSCF
Φi (1)
i

HSCF

HSCF (1) = h(1) +

m
X

(Ji (1) − Ki (1))

i

εi

Φi

h

N

h(1) =

−4µ X ZI

2
rµI
I=1

Φi