3 Postdoc positions in Electrochemistry (Grenoble) .pdf


Nom original: 3 Postdoc positions in Electrochemistry (Grenoble).pdfAuteur: Marcello Gennari

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THREE 2-YEAR POSTDOCTORAL POSITIONS IN CHEMISTRY
AT THE UNIVERSITY GRENOBLE ALPES
Three 2-year postdoctoral positions in chemistry are available at Grenoble. These projects concern
the development of molecular catalysts for multi-electron reduction of small earth-abundant
molecules (H+, CO2, N2).
Project 1: This project aims at developing catalytic systems for CO2 chemical valorization, based
on non-noble metals, through the development of molecular complexes inspired from the
biological Ni(Fe)-based catalysts present in CODH and ACS that catalyze CO2 reduction and
carbonylation reactions, respectively. The objectives are to develop structural and functional
mimics of these enzymes and to understand their catalytic mechanism to highlight the key elements
required for an optimal reactivity.
Project 2: The objective is to develop molecular materials for mild electrocatalytic N2 reduction
to ammonia, by incorporating well-known molybdenum-PNP complexes in electrode-supported
mesoporous materials, such as multiwall carbon-nanotubes mesh and metal/porous organic
frameworks. Confinement is expected to be beneficial for both stability and reactivity of the
catalysts.
Project 3: It aims at developing bio-inspired H2 evolution catalysts, with two major objectives (i)
contributing to the full understanding of the catalytic mechanism of the [NiFe] hydrogenase and
(ii) developing efficient mimics of this enzyme that model not only the structure and function of
the active site but also its impressive reactivity. More specifically we will focus on the synthesis
of series of dithiolato-bridged heterobimetallic NiFe complexes to determine structure/reactivity
correlation and on the characterization of intermediate species.
Profiles: PhD in inorganic chemistry with a good experience in organic synthesis and
coordination/organometallic chemistry (synthesis under inert atmosphere, characterization of
metal complexes with different spectroscopic techniques, reactivity studies). Knowledge in
electrochemistry will be appreciated. Experience in catalysis and/or electrocatalysis is welcome.
For project 2, knowledge in solid-state characterization techniques will be also appreciated.
Contacts:
Projects 1 & 3:
Project 2:

Carole DUBOC, carole.duboc@univ-grenoble-alpes.fr
Vincent ARTERO, vincent.artero@cea.fr
Marcello GENNARI, marcello.gennari@univ-grenoble-alpes.fr,
Matthieu KOEPF, matthieu.koepf@cea.fr

Duration: 2 years (1+1), starting as soon as possible
Websites:
http://dcm.ujf-grenoble.fr/DCM-SITE/CIRE/index.php?page=/DCM-SITE/CIRE/metal-sulfur
http://www.solhycat.com/
Funding sources: LaBEX Arcane (https://www.labex-arcane.fr/) & ANR


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